Original
The first FluoroQuinolone was made in 1980 called Cipro, which is in the same family if Quinolones that have been around since 50s-60s or earlier. Many Quinolones where blackboxes and pulled off the market for seriously damaging and killing the patients it was dispose to help. The ones that survived had Fluoride added to it ... thus the FluoroQuinolones were born .... but still today there are Quinolones and same family... much research is need to know more. But this is a good start of brief history. I hope this helps a bit.